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The activation of BM achieves optimal effect when using 1 mol/L oxalic acid solution with a liquid-solid ratio of 2:1. The TCLP and BCR test results show that the ABM significantly outperforms the BM in terms of Pb immobilization.
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5 days agoThe D418 resin has the function group of [-NHCH 2 PO 3 H 2] and its structure is shown in Fig.1.The exhausted D418 resins were obtained from the ion exchange treatment process of the acid leaching solution of black shale .The vanadium adsorption capacity on the exhausted D418 resin is just about 80% of total adsorption capacity of fresh D418 resin.
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The leaching experiments were carried out using 250 mL flasks with a mixture of 10 g of clay and 100 mL of oxalic acid. The flasks were placed on heating plates with constant agitation (870 rpm). The amount of leached iron after this procedure was determined by atomic absorption spectroscopy.
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In this study, oxalic acid showed better performance than inorganic acid in the indium leaching system from waste liquid crystal displays. The In 3+ leaching efficiency with the powder dosage of 50 g/L came up to 100% within 45 min, using 0.5 M oxalic acid and stewing at 70 °C. Ultrasonic cavitation can improve the powder dosage.
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In this work, we developed a novel recovery process, only combined with oxalic acid leaching and filtering. When the optimal parameters for leaching process is controlled at 150 min retention time, 95 °C heating temperature, 15 g L(-1) solid-liquid ratio, and 400 rpm rotation rate, the recovery rate of lithium and cobalt from spent LIBs can ...
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Recovery of Oxalic Acid From Oxalic Acid Leaching of Diatomaceous Earth by Use of Electrodialysis. Shigen-to-Sozai doi 10.2473/shigentosozai.111.569. Full Text Open PDF Abstract. Available in full text. Date. January 1, 1995. Authors Hiroshi TAKAHASHI Shigenobu KIDA Ken-ichi KIKUCHI Takuo SUGAWARA.
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Sahoo et al. (2001) studied the leaching of low-grade manganese ore using oxalic acid as reductant in sulphuric acid solution. The results showed that the recovery of manganese was 98.4% in the conditions of 30.6 g/l oxalic acid, 0.543 mol/L sulfuric acid after 105 minutes of leaching at pulp temperature of 85 °C (Sahoo et al., 2001).
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Reactivity Profile. OXALIC ACID is hygroscopic and sensitive to heat. This compound may react violently with furfuryl alcohol, silver, sodium, perchlorate, sodium hypochlorite, strong oxidizers, sodium chlorite, acid chlorides, metals and alkali metals. (NTP, 1992). The heating of mixtures of Oxalic acid and urea has lead to explosions.
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Oxalic acid's main applications include cleaning or bleaching, especially for the removal of rust (iron complexing agent). Its utility in rust removal agents is due to its forming a stable, water-soluble salt with ferric iron, ferrioxalate ion. The cleaning product Zud contains oxalic acid. [51]
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TodayOxalic acid serves almost all major end-use industries, including water treatment chemicals, petrochemicals, pharmaceuticals, and others. According to a recent Future Market Insights (FMI) study, the global oxalic acid is expected to reach the valuation of US$ 1,191.0 Mn by 2028. The industrial sector in Asia Pacific is growing at a substantial rate, thereby increasing the demand for oxalic ...
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If you have mainly iron and at low concentration (max. about 100 ppm), you may get away with an oxalic leaching as a first step - test and see. If you have higher iron, not to mention other deleterious elements (Ba, Mg, Al, Ca, Ti, Zr, etc.) you may want to consider hydrochloric acid leaching. Sulfuric acid will not dissolve barium.
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In this study, oxalic acid showed better performance than inorganic acid in the indium leaching system from waste liquid crystal displays. The In3+ leaching efficiency with the powder dosage of 50...
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The highest oxalic acid yield and the maximum oxalic acid concentration at the end of this experi-ment were achieved in glucose medium, that were 0.387 (75.49 % of theoretical oxalic acid yield) and 14.67 g/L of oxalic acid. Those results were far from theoretical yield (below 90%). There were some possible reasons for it. First, perhaps there
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Step 1 - Removing the Rust The simplest way to get rid of rust is to use oxalic acid. You'll need a fairly concentrated solution of about 1 pound of acid per gallon of water. Apply it to the rusted areas as a spray using a hose with a spray bottle attachment. The rust should just drain away.
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Selectively leach NMC powder with oxalic acid (0.6 M, 50 mL/g, and 70°C for 10 min) 2. Grind dry powder with Li 2 CO 3 and sinter at 900°C for 14 h; ... the main equipment required are the leaching reactor, mixer-settler units for extraction and stripping, and auxiliary solvent reservoirs. Nevertheless, the feasibility of LIB recycling must ...
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The tremendous consumption of lithium-ion batteries (LIBs) raises concern about sustainable resources especially for the valuable metals. Recycling valuable metals from spent LIBs is expected to meet the demand growth of LIBs. Herein, a novel approach combined with oxalic acid leaching, calcination relithiation, and annealing is proposed to regenerate spent LiNi0.5Co0.2Mn0.3O2 (NCM523 ...
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Acid leaching of ilmenite ore was carried out using HCl acid with a concentration of 37% (w/w) and oxalic acid with a concentration of 99% (w/w) in a 300 cm 3 three-neck glass reactor equipped with a reflux condenser and a mechanical agitator with Teflon-coated stirring rod.
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The invention relates to an ultrasonic-assisted method for leaching potassium at low temperature under normal pressure, which comprises the following steps: crushing and grinding: crushing and grinding potash feldspar ore until the fineness is about 150 meshes: acid-ore mixing: adding 5-15mL of phosphoric acid-organic acid mixed solution to every gram of potash feldspar, and uniformly mixing ...
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This selective leaching behavior may be attributed to differences in dissolvability at low temperatures. This is because, while the dissolvability of iron (II) oxalate is 293 K 0.008 g/100 g water,...
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The primary advantage of using oxalic acid is in the formation during leaching of soluble complexes that are both photochemically and microbiologically degradable. In this study, chemical leaching. 12 Optimization and kinetics of oxalic acid treatment of feldspar for removing the iron oxide impurities K. Pariyan, M. Hosseini, A. Ahmadi, A. Zahiri
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Methods for the extraction of metals such as rare earth metals and thorium from metal compounds and solutions. The methods may include the selective precipitation of rare earth elements from pregnant liquor solutions as rare earth oxalates. The rare earth oxalates are converted to rare earth carbonates in a metathesis reaction before being digested in an acid and treated for the extraction of ...
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Moreover, R. phaseoli mainly secreted organic acids, such as oxalic acid and citric acid. Oxalate anions contain strong and stable electrons, and each citric acid molecule can ionize three hydrogen ions. Thus, both oxalic acid and citric acid are strong organic acids that could damage mineral lattices to release copper ions into the leaching ...
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In many instances total-rock and sieved-soil and stream-sediment samples lack the sensitivity and contrast required for reconnaissance exploration and necessary in the search for blind ore deposits. Heavy-mineral concentrates incorporate the required sensitivity and contrast but are overly expensive for two reasons: time-consuming sample preparation is required to obtain them, and they cannot be e
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The gold-bearing residue was leached in dilute aqua regia to solubilize the gold. High-purity gold was precipitated from the aqua regia solution with oxalic acid, sulfurous acid, sodium bisulfite, and gaseous sulfur dioxide. The leaching-precipitation experiments recovered 99.9 pct of the gold.
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Aug 4, 2021As the oxalic acid amount is dependent on the concentration and oxidation state of iron in the leachate, for each pilot-scale batch, the optimum amount of oxalic acid should be evaluated empirically. On the other hand, in the case of NiMH black mass leachate, the situation was more similar to PMS oxalate precipitation than SPM since a minimum ...
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Jun 29, 2022In this work, we propose a rapid and facile method (oxalic acid leaching under microwave-assisted conditions) to study the simultaneous recovery of vanadium (V) and nickel (Ni) from spent fluid catalytic cracking (SFCC) catalysts. The central issue in all of these studies is to test the modeling and experimental results of excellent fitting effects of leaching parameters. In order to maximize ...
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the invention belongs to ito glass substrate technical field of resource recovery, and in particular to a kind of method that oxalic acid leaches indium in ito glass substrate.this method...
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Aug 12, 2021glyoxylic acid esters can be polymerized with bases to obtain biodegradable polymers with chelating properties. 60, 61 many monomers for sustainable polymers can be derived from it, linking the consumption of co 2 with the production of circular, potential long-term carbon storage in materials. 62 a detailed account from our group on polyesters .
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Oxalic acid is an extremely effective iron stain remover. It reacts extremely well to iron and forms double bonded pool water soluble compounds (referred to as "chelation"). The iron is then trapped in these dissolved compounds where they're less likely to form stains again. We recommend Silver Pool Stains At a glance U Light gray to black
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Oxalic Acid 144 -62 -7 99 -100 1 mg/m³ 1 mg/m³ 2 mg/m³ Section III - Hazard Identification ... Oxalic Acid Page 3 sparking tools and equipment. Pick up spill for recovery or disposal and place in a ... likely to leach to groundwater. Biodegrades at moderate rate. Rapid volatilization .
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Apr 14, 2021Under optimized leaching conditions (0.8 M oxalic acid concentration, 85°C reaction temperature, 1.75 ambient pH, 106+75 μm particle size, 15% w/v solids concentration and 150 min. leaching time) with 250 rpm stirring, 83.90% of Fe2O3 was removed. The amount of iron oxide, the main impurity in the clay, has been reduced from 2.70 to 0.40%.
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Leaching experiments Small glass vials (4 mL) were filled with a fixed amount of [Hbet] [Tf 2 N] (1 g) and 10 mg of roasted magnet particles which resulted in a solid/liquid ratio of 10 mg g −1. Water-containing ionic liquid (2.5-10 wt%) or a 1 : 1 wt/wt [Hbet] [Tf 2 N]-H 2 O mixture was used depending on the experiment.
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Experimental Materials Equipment and Procedures. ... SX/EW technology application to process and recover copper from dilute sulfuric acid leach liquors is expanding and Kelex has the thermal stability necessary for hydrogen stripping as noted by Demopoulos (1981) in his investigation. ... Oxalic acid precipitation stripping a DEHPA-based ...
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Jul 6, 2022Mix 12 to 16 ounces of oxalic acid powder to 1 gallon of hot water in a clean plastic bucket. Mix thoroughly until all of the grains are mixed in. Since oxalic acid reacts when exposed to metal, be sure to use a plastic bucket only and do not mix with any metal implements. Mix with a wood stick or by hand (while wearing waterproof gloves).
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It helps remove protein deposits, hard water scale, beer and milk stone, copper corrosion, and light rust. Some other uses of sulfamic acids are listed below. • Descaler, rust remover, and cleaner. • Descaler and cleaner for dairy equipment such as milk evaporators, milkers' pipeline. • Descaler and cleaner for brewery equipment such as ...
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addition of ascorbic acid to citric acid as a leaching agent led to a reduction in the leaching efficiency. This is because the leaching ability of ascorbic acid is lower, but the pH and pK a are higher, compared to citric acid. At a concentration of 1mol/L, citric acid has a pH of 1.29 and a pK a of 3.17, whereas ascorbic acid has a pH of 1.88 ...
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A suspension of chrysotile asbestos fibres in aqueous 0.5 M oxalic acid was subjected to power ultrasound with the aim to disrupt and detoxify the mineral by the leaching action of oxalic acid on its structural cations acting simultaneously with a
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of oxalic acid used to the number of moles of cobalt ions in the solution. After determining the optimum pH value where the extraction is maximum, the molar ratio was investigated at 2:1, 3:1
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This result was attributed to the passivation of pyrite coated with FeC 2 O 4 ·2H 2 O, which can block the reaction between pyrite and oxalic acid. For the BRAL process, 86.8% of V and 35.2% of Fe impurity were recovered after leaching for 4 h at 95 °C with a 1.0 L/kg water-mineral ratio, a 6.0 mol/kg oxalic acid dosage and a 5 wt % CaF 2.
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30 mg. Dried Figs. 5 pieces. 24 mg. Dried Prunes. 5 prunes. 11 mg. As shown above, dried figs, pineapple, and prunes contain relatively high amounts of oxalate. Furthermore, any dried versions of oxalate-rich fresh fruit (see next section) will also contain high concentrations.
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