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The Recovery of nickel from lateritic ores as the main oxide resources has been always debated. Since it consists of 1.74% Ni, 0.14% Co and 40.8% Fe, co-dissolution of iron occurred by using common lixiviation like sulfuric acid. Therefore, some leaching agents should be sought due to promoting a high dissolution of nickel/cobalt and a negligible iron recovery. This research investigates the ...
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Jun 2, 2022The process of Leaching is used to concentrate the ore. The ore of the metal is made to react with a suitable chemical reagent leading to the dissolution of only the metal, leaving behind the impurities which remain undissolved. The solution so obtained is a compound of the metal that can be further processed to extract the pure metal.
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It was found that a maximum zinc extraction (95% Zn) was obtained at a 4.5 M concentration of sulphuric acid in 3 h leaching at 70°C, keeping the solid:liquid weight ratio at 1:5 Iron and ...
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Gravity and electro-magnetic concentration procedures useful in connection with these ores are described. Commercial uranium extraction is accomplished by leaching the ore with a solution composed of sulfuric acid and manganese dioxide in the presence of ferric sulfate. Recoveries of abovt 80% of the uranium contained in the ore aremore »
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The process of producing iron oxide from sulfuric acid waste residues. In the waste residue produced, except for a small amount of impurities insoluble in sulfuric acid, it is mainly composed of unacidified ilmenite, which is discharge after treatment. For the sludge treatment method, the plate and frame filter is generally used.
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existing mathematical models of heap leaching. Sulfuric acid curing is a pretreatment to accelerate the extraction kinetics of copper ores and is widely used in copper operations. The curing process involves the addition of a highly concentrated sulfuric acid to the copper ore during agglomeration. Then, chemical reactions already begin prior to
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Manganese ore was also analyzed by thermal analysis to observe their thermal decomposition character. In this study, sulphuric acid (H 2 SO 4, 6 M) was deployed as leaching agent. The leaching process was performed at 90 °C for two hours with the addition of NH 4 OH to control pH. Recovery percentage of leaching process yielded of 87 % Mn ...
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INVESTIGATION OF THE OPTIMUM DISSOLUTION TEMPERATURES OF PHOSPHORUS IN SULPHURIC, NITRIC AND OXALIC ACID SOLUTIONS DURING LEACHING OF IRON OXIDE ORE Authors C. I. NWOYE R. A. EJIMOFOR C. C. NWAKWUO O. O. ONYEMAOBI Publication date 2009 Publisher Taylor's University Abstract
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In addition to the oxide copper minerals being dissolved by the sulfuric acid generated by the reaction of ferric iron with the sulfides, if sulfuric acid has been added to the leach solution this acid will also dissolve copper from the oxide minerals. Chalcocite will dissolve completely and the sulfide sulfur will be converted to sulfate.
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Abstract: In this study, the effects of acid/ore ratio (0.1-0.6 g H 2 SO 4 /g dry ore), leaching temperature (200-240 °C) and leaching time (30-120 minutes) on the high pressure sulphuric acid leaching of a lateritic nickel ore sample having 1.37% Ni, 0.076% Co and 47.72% Fe 2 O 3 were investigated. The
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The growing demand of copper metal in the world continues to push the limit of utilization of complex copper resources, among which the iron oxide associated with copper-gold-uranium ore deposits (IOCG-U) contain economic copper and abundant gangues including uranium-bearing minerals that carry naturally occurring radionuclides and pose a challenge for public health and environment. To ...
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during leaching of iron oxide ore in sulphuric acid solution. Results of the investigations show that the optimum leaching temperature, grain size, and initial pH are 550C, 0.1mm and 6.8 respectively. The optimum initial solution temperature (just before commencement of the leaching process) required for
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Therefore, the sulfuric acid leach residue was 0.52% copper, of which 0.30% was undissolved native copper. The remaining copper may be assumed to be a sulfide copper with low solubility in sulfuric acid under the operational conditions. The sulfuric acid leaching residue was neutralized with a sodium hydroxide solution and submitted to cyanidation.
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The results of the leaching experiment revealed that the mechanical activation treatment favors the extraction of iron (Fe) and titanium dioxide (TiO 2) from the VTMCs. The Fe and TiO 2 extractions from the mechanically activated sample after 10 h compared with the unactivated sample were increased by 12.82% and 4.73%, respectively.
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(2006). Study on the kinetics of iron oxide leaching by oxalic acid. (2000). Sulphuric acid pressure leaching of laterites -speciation and prediction of metal solubilities at temperature. (2003). Synthesis and characterization of goethite and goethite-hematite composite: experimental study and literature survery. (1979).
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Oxide Method 1 1.000 gram of pulverized sample,digestion in long tube with 15 ml of 5 percent sulfuric (H2S04) acid on shaking table at room temperature (25°C) for one hour.Then centrifuge sample and decant solution to 200 ml flask.
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Copper recovery changed from 25.5% to 58.9% while iron recovery changed from 4.7% to 15.2%. Acid consumption were achieved between 18 to 54 kg per ton of ore. Acid solution concentration and irrigation flow rate are the most important parameters on the copper and iron recoveries.
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leaching from low grade copper oxide ore by sulphuric acid, and they have obtained leaching percent of cop-per over 90%. Compared with the copper leaching effi-ciency of about 35% in the mill running technology the leaching process has achieved a better economic result. In the present study the leaching of oxide-sulfide
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This paper presents an assessment evaluation of sulphur removal based on as-beneficiated sulphur content and leaching temperature during iron ore processing in acetic acid solution. The acid solution and ore contained in the reaction vessel were allowed to react at a temperature range: 30-600C for 40 minutes.
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Preliminary investigations on alkali leaching kinetics of. sample was subjected to leaching with (i) a mixture of oxalic acid and ascorbic acid,(ii) hydrochloric acid,and finally (iii) sulfuric acid.Acid leaching of ilmenite was carried out using a 250 cm3 necked glass reactor provided with a reflux condenser and a mechanical agitator with teflon coated stirring rod.During leaching,the pulp
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Jan 15, 2021Central composite design (CCD) method was used to design leaching experiments and the optimum conditions were found as follows: 30% of solid fraction, 22.05% sulphuric acid concentration, and the...
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NaCl and NaF were added to 4.0M sulphuric acid solution prior to adding the ore sample. The tests were conducted at 25oC and with a leaching period of 240 min. Sulphuric acid concentration, particle size, percentage solids, and stirring speed were kept constant at 4.0M, -45 µm, 10%, and 700 r/min respectively.
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dissolved phosphorus (relative to the final pH of the leaching solution) during leaching of iron oxide ore in oxalic acid solution. It was observed that the validity of the model is rooted in the relationship lnP = N/α where both sides of the expression are approximately equal to 4. The model expressed as P = e12.25/α (5)
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May 1, 2022For the iron mineral bakes, leaching was conducted in water at a liquid to solid ratio ( w /w) of 20:1 and controlled at pH < 1 by addition of concentrated sulfuric acid if required. Although the leach medium after the iron mineral bakes was less acidic than for the monazite/iron mineral bakes, trends can be compared.
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of colonies were counted. Numbers of viable iron- and sulfur-oxidising bacteria were estimated. 2.3. Column bioleaching Representative, accurately weighed 10 kg portions of ore were acid conditioned with 900 mL dilute sulfuric acid (pH 1.8) or with water (pH 7) to agglomerate any fine particles.
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as copper, nickel, and iron are recovered as cathode powder. The copper was found to be cuprous oxide (Cu 2O) and ele- ... reported to be about 50% in the case of leaching in sulfuric acid solution without other oxidants7-9). Although Sullivan ... Cuprous oxide and sulfuric acid used in the ex-periments were of reagent grade. As shown in Fig ...
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Sep 18, 2020In case we add water to sulphuric acid, since the water is lighter than sulphuric acid, it will stay at the top. Hence, we will have water in the top layer and sulphuric acid in the bottom layer. At the interface the sulphuric acid will absorb water and release heat. This released heat will evaporate a fraction of water near the interface.
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The coupled leaching of ocean polymetallic nodule and low-grade nickel sulphide ore in sulphuric acid solution was investigated, especially in performance on selective extraction of Ni, Cu, Co, and Mn. This work can be divided into three parts. First, the advantageous selective metal extraction conditions, parallel to the optimal coupled leaching conditions, were measured by coupled leaching ...
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The aim of the research work was to study the specific process of hydrofluoric acid decomposing (Fe,Mn)(Nb,Ta) 2 O 6 mineral structure. In this paper, X-ray photoelectron spectroscopy (XPS), density functional theory (DFT) calculations combining with leaching experiments were used to study the atoms bonding, charge transfer, and energy changes on the mineral/liquid interface and selective ...
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The residue is composed of 40.1% Fe, 33.4% SiO 2, 8.31% Al 2 O 3, 0.08% P, and 0.34% MnO. The developed process of silica and iron recovery consisted of size classification, magnetic separation, and removal of impurities by leaching. A concentration of SiO 2 from 33.4% to 67.0%, with 60.0% of mass reduction, was achieved by size classification.
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The last step results in zinc sulfide ore concentrate which consists of 50 zinc, 32% sulfur, 13% iron, and 5% SiO2. The concentrate is later roasted to obtain zinc oxide along with sulfur dioxide. The latter is used to produce sulfuric acid which is necessary for the leaching process.
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Model for predictive analysis of the concentration of phosphorus removed (relative to the initial and final pH of the leaching solution) during leaching of iron oxide ore in sulphuric acid solution has been derived. It was observed that the validity of the model is rooted in the mathematical expression; (P/N)1/3 = (er/a) where both sides of the relationship are almost equal.
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Nwoye et al [7] derived a model for predicting the concentration of dissolved iron during leaching of iron oxide ore in sulphuric acid solution. The model is stated as; %Fe = 0.35(α/T)3 (2) Where T = Solution temperature at the time t, when the concentration of dissolved iron is evaluated.
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By reacting copper (II) oxide, a black solid, with colourless dilute sulfuric acid, they produce copper (II) sulfate with a characteristic blue colour. Students can then obtain blue copper (II) sulfate pentahydrate crystals. Using the procedure below, it should take no more than 30 minutes to produce the filtered salt solution. Experimental ...
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Bioleaching involves the use of microorganisms to catalyze the oxidation of iron sulfides to create ferric sulfate and sulfuric acid. Ferric sulfate, which is a powerful oxidizing agent, then oxidizes the copper sulfide minerals and the copper contained is then leached by the sulfuric acid formed.
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The iron oxides in the ilmenite are substantially removed by leaching the ilmenite with a mineral acid, such as hydrochloric acid, sulfuric acid, etc. Usually, the iron oxides in the ilmenite are present in both ferric and ferrous forms. Some ores contain high percentages of ferric oxide (Fe.sub.2 O.sub.3), and some, ferrous oxide (FeO).
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The Open Mineral Processing Journal The leaching of dolomitic-copper ore using sulphuric acid under controlled conditions was studied with a view to evaluating the economic value and the effect of ore pulverisation, particle size, temperature and pH on the recovery of copper from chalcopyrite.
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Experiments of direct leaching were performed with the parameters of temperature and sulphuric-acid con- centration under atmospheric pressure for 360 min. The parameters and menu
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The sulfation-roasting-leaching process has the potential to change this scenario once it can be applied to all kinds of nickel laterite ores and does not consume much acid, as in the atmospheric leaching process. The main characteristic of the process is the iron sulfates decomposition during roasting steps, which produces sulfur trioxide (SO 3 ).
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May 7, 20212. Even the low sulphuric acid density (2.5 wt%) removed the iron impurities; leaching kinetics of copper were quite fast compared with Zn and, showed more than 90 % copper leach. 3. The target metal copper was leached above 90% at room temperature whereas other metals like zinc and iron did not reach 90%. 4.
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